
members of the Johnson Lab,
summer 2007 |
We are interested in
exploring fundamental
chemical paradigms for charge accommodation and transport mediated by
solvent in a regime where each solvent molecule counts. Our
approach involves building custom laser spectrometers that rely on "ion
bunching" mass spectrometry to isolate a precise number of solvent
molecules around a solute ion. The nature of the excess
proton
and electron in water are of special interest because it has been
difficult to explain their behaviors in the macrosopic scale,
and
clusters provide us with qualitatively new pictures of how to think
about them. Reaction intermediates and nanoscale water are
also
under study, and we have very recently initiated a new
apparatus
designed to study water-mediated chemistry at play in Earth's
atmosphere.