Hazari Group

Publications

62. Bielinski, E. A.; Dai, W.; Guard, L. M.; Hazari, N.; Takase, M. K. 'Synthesis, Properties and Reactivity Studies of Palladium and Nickel NHC Complexes Supported by Combinations of Allyl, Cyclopentadienyl, and Indenyl Ligands.' Organometallics 2013, In Press.

61. Guard, L. M.; Hazari, N. 'Synthesis and Reactivity of Magnesium Complexes Supported by Tris(2-dimethylaminoethyl)amine (Me6tren).' Organometallics 2013, In Press.

60. Bernskoetter, W. H.; Hazari, N. 'A Computational Investigation of the Insertion of Carbon Dioxide into Four and Five Coordinate Iridium Hydrides.' Eur. J. Inorg. Chem. 2013, In Press. Invited contribution to 'Small Molecule Activation by Reactive Metal Complexes' issue.

59. Jin, D.; Schmeier, T. J.; Williard, P. G.; Hazari, N.; Bernskoetter, W. H. 'Lewis Acid Induced β-Elimination from a Nickelalactone-Efforts Toward Acrylate Production from CO2 and Ethylene.' Organometallics 2013, 32, 2152-2159.

58. Huang, J.-S.; Goh, T.; Li, X.; Sfeir, M.; Bielinski, E. A.; Tomasulo, S.; Lee, M. L.; Hazari, N.; Taylor, A. D. 'Polymer Bulk Heterojunction Solar Cells Employing Förster Resonance Energy Transfer.' Nat. Photonics 2013, In Press.

57. Wu, J.; Dai, W.; Farnaby, J. H.; Hazari, N.; Le Roy, J. J.; Mereacre, V.; Murugesu, M.; Powell, A. K.; Takase, M. K. 'Synthesis and Catalytic Activity of Iron Complexes with Bidentate NHC Ligands.' Dalton Trans. 2013, 42, 7404-7413. Invited contribution to 'N-Heterocyclic Carbene' issue.

56. Collom, S. L.; Anastas, P. T.; Beach, E. S.; Crabtree, R. H.; Hazari, N.; Sommer, T. 'Differing Selectivities in Mechanochemical versus Conventional Solution Oxidation using Oxone.' Tetrahedron Lett. 2013, 54, 2344-2347.

55. Durrell, A. C.; Jackson, M. N.; Hazari, N.; Gray, H. B. 'Making Carbon-Chlorine Bonds by Dipalladium Electrocatalysis.' Eur. J. Inorg. Chem. 2013, 1134-1137.

54. Dau, P. D.; Hruszkewcyz, D. P.; Huang, D.-L.; Chalkley, M. J.; Liu, H.-T.; Green, J. C.; Hazari, N.; Wang, L.-S. 'Photoelectron Spectroscopy of Pd(I) Dimers with Bridging Allyl Ligands.' Organometallics 2012, 31, 8571-8576.

53. Suh, H. W.; Schmeier, T. J.; Hazari, N.; Kemp, R. A. 'Experimental and Computational Studies of the Reaction of Carbon Dioxide with Pincer Supported Nickel and Palladium Hydrides.' Organometallics 2012, 31, 8225-8236.

52. Graeupner, J.; Brewster, T. P.; Blakemore, J. D.; Schley, N. D.; Thomsen, J. M.; Brudvig, G. W.; Hazari, N.; Crabtree, R. H. 'Preparation of Electron-Rich CpIr(biphenyl-2,2’-diyl) Complexes with p-Accepting Carbon Donor Ligands.' Organometallics 2012, 31, 7158-7164.

51. Dobereiner, G. E.; Wu, J.; Manas, M. G.; Schley, N. D.; Takase, M. K.; Crabtree, R. H.; Hazari, N.; Nova, A.; Maseras, F. 'Mild, Reversible Reaction of Iridium(III) Amido Complexes with Carbon Dioxide.' Inorg. Chem. 2012, 51, 9683-9693.

50. Luca, O. R.; Blakemore, J. D.; Praetorius, J. M.; Schmeier, T. J.; Hunsinger, G. B.; Brudvig, G. W.; Hazari, N.; Crabtree, R. H. 'Nickel Pincer Complexes for the Electrocatalytic Production of Hydrogen.' Inorg. Chem. 2012, 51, 8704-8709.

49. Guard, L. M.; Palma, J. L.; Stratton, W. P.; Allen, L. J.; Brudvig, G. W.; Crabtree, R. H.; Batista, V. S.; Hazari, N.; 'Synthesis and Computational Studies of Mg Complexes Supported by 2,2':6,2''-Terpyridine Ligands.' Dalton Trans. 2012, 41, 8098-8110. Invited contribution to 'New Talent in the America's Issue'.

48. Schmeier, T. J.; Nova, A.; Hazari, N.; Maseras, F. 'Synthesis of PCP Supported Nickel Complexes and their Reactivity with Carbon Dioxide.' Chem. Eur. J. 2012, 18, 6915-6927.

47. Wu, J.; Faller, J. W.; Hazari, N.; Schmeier, T. J. 'Stoichiometric and Catalytic Reactions of Thermally Stable Ni(0) NHC Complexes.' Organometallics, 2012, 31, 806-809 .

46. Hazari, N.; Labinger, J. A.; Igelsia, E: Simenotti, D. A. 'Selective Homogeneous and Heterogeneous Catalytic Conversion of Methanol/Dimethyl Ether to Triptane.' Acc. Chem. Res. 2012, 45, 653-662 .

45. Hruszkewycz, D. P.; Wu, J.; Green, J. C.; Hazari, N.; Schmeier, T. J. 'Mechanistic Studies of the Insertion of CO₂ into Palladium(I) Bridging Allyl Dimers.' Organometallics 2012, 31, 470-485. For more information on this work see: Patton, R. S.; Brown, J. M. 'Dinuclear Palladium Complexes – Precursors of Catalysts?' Angew. Chem. Int. Ed. 2012, 51,10448-10450.

44. Ashley, J. M.; Farnaby, J. H.; Hazari, N.; Kim, K. E.; Luzik Jr, E. D.; Meehan, R. E.; Meyer, E. B.; Schley, N. D.; Schmeier, T. J.; Tailor, A. N. 'Axially Chiral Dimeric Ir and Rh Complexes Bridged by Flexible NHC Ligands.' Inorg. Chim. Acta 2012, 380, 399-410. Invited contribution to 'Young Investigator Award Issue'.

43. Brewster, T. P.; Ding, W.; Schley, N. D.; Hazari, N.; Batista, V. S.; Crabtree, R. H. 'Thiocyanate Linkage Isomerism in a Ruthenium Polypyridyl Complex.' Inorg. Chem. 2011, 50, 11938-11946.

42. Aitken, G.; Hazari, N.; Frey, A. S. P.; Cloke, F. G. N.; Summerscales, O.; Green, J. C. 'Reductive Coupling of Carbon Monoxide by U(III) Complexes – a Computational Study.' Dalton Trans. 2011, 40, 11080-11088. Selected as a hot article by the editors of Dalton Trans.

41. Schmeier, T. J.; Dobereiner, G. E.; Crabtree, R. H.; Hazari, N. 'Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO₂ Reduction Catalyst.' J. Am. Chem. Soc. 2011, 133, 9274-9277.

40. Wu, J.; Hazari, N.; Incarvito, C. D. 'Synthesis, Properties and Reactivity with Carbon Dioxide of (allyl)₂Ni(L) Complexes.' Organometallics 2011, 30, 3142-3150.

39. Hazari, N.; Hruszkewycz, D. P.; Wu, J. 'Pd(I) Bridging Allyl Dimers: A New System for the Catalytic Functionalization of Carbon Dioxide.' Synlett 2011, 13, 1793-1797. Invited SYNPACT review article.

38. Dobereiner, G. E.; Nova, A.; Schley, N. D.; Hazari, N.; Miller, S. J.; Eisenstein, O.; Crabtree, R. H. 'Iridium-Catalyzed Hydrogenation of N-Heterocyclic Compounds under Mild Conditions by an Outer Sphere Pathway.' J. Am. Chem. Soc. 2011, 133, 7547-7562.

37. Blakemore, J. D.; Chalkley, M. J.; Farnaby, J. H.; Guard, L. M.; Hazari, N.; Incarvito, C. D.; Luzik Jr, E. D.; Suh, H. W. 'New Bidentate Trans-Chelating N-Heterocyclic Carbene Ligands for Palladium.' Organometallics 2011, 30, 1818-1829.

36. Hruszkewycz, D. P.; Wu, J.; Hazari, N.; Incarvito, C. D. 'Palladium(I) Bridging Allyl Dimers for the Catalytic Functionalization of CO₂.' J. Am. Chem. Soc. 2011, 133, 3280-3283. Selected as a Science and Technology Concentrate in Chemical & Engineering News.

35. Brewster, T. P.; Blakemore, J. D.; Schley, N. D.; Incarvito, C. D.; Hazari, N.; Brudvig, G. W.; Crabtree, R. H. 'An Iridium(IV) Species, [Cp*Ir(NHC)Cl]⁺, Related to a Water-Oxidation Catalyst.' Organometallics 2011, 30, 965-973.

34. Marino, N.; Fazen, C. H.; Blakemore, J. D.; Incarvito, C. D.; Hazari, N.; Doyle, R. P. 'Isostructural Pd^II and Pt^II Pyrophosphato Complexes: Polymorphism and Unusual Bond Character in d⁸-d⁸ Systems.' Inorg. Chem. 2011, 50, 2507-2520.

33. Shuman, N. S.; Miller, T. M.; Viggiano, A. A.; Luzik Jr, E. D.; Hazari, N. 'Kinetics of Electron Attachment to SF₃CN, SF₃C₆F₅, and SF₃ and Mutual Neutralization of Ar⁺ with CN^- and C₆F₅^-.' J. Chem. Phys. 2011, 134, 044323/1-044323/7.

32. Schmeier, T. J.; Hazari, N.; Incarvito, C. D.; Raskatov, J. R. 'Exploring the Reactions of CO₂ with PCP Supported Nickel Complexes.' Chem. Commun. 2011, 47, 1824-1826.

31. Wu, J.; Hazari, N. 'Palladium Catalyzed Carboxylation of Allylstannanes and Boranes Using CO₂.' Chem. Commun. 2011, 47, 1069-1071.

30. Shuman, N. S.; Miller, T. M.; Hazari, N.; Luzik Jr, E. D.; Viggiano, A. A. 'Kinetics Following Addition of Sulfur Fluorides to a Weakly Ionized Plasma from 300 K to 500 K: Rate Constants and Product Determinations for Ion-ion Mutual Neutralization and Thermal Electron Attachment to SF₅, SF₃, and SF₂^-.' J. Chem. Phys. 2010, 133, 234304/1-234304/11.

29. Wu, J.; Green, J. C.; Hazari, N.; Hruszkewycz, D. P.; Incarvito, C. D.; Schmeier, T. J. 'The Reaction of Carbon Dioxide with Palladium Allyl Bonds.' Organometallics 2010, 29, 6369-6376.

28. Hazari, N. 'Homogeneous Iron Complexes for the Conversion of Dinitrogen into Ammonia and Hydrazine.' Chem. Soc. Rev. 2010, 4044-4056.

27. Durrell, A. C.; Gray, H. B.; Hazari, N.; Incarvito, C. D.; Liu, J.; Yan, E. C. 'Tris(hydroxypropyl)phosphine Oxide: A Chiral 3D Material with Non-Linear Optical Properties.' Cryst. Growth Des. 2010, 10, 1482-1485.

26. Bercaw, J. E.; Durrell, A. C.; Gray, H. B.; Green, J. C.; Hazari, N.; Labinger, J. A.; Winkler, J. R. 'Electronic Structures of Pd(II) Dimers.' Inorg. Chem. 2010, 49, 1801-1810.

25. Oblad, P. F.; Hazari, N.; Labinger, J. A.; Bercaw, J. E. 'Oxidation of Organometallic Platinum and Palladium Complexes Obtained from C-H Activation.' Organometallics 2010, 29, 789-794.

24. Weinberg, D. R.; Hazari, N.; Labinger, J. A.; Bercaw, J. E. 'Iridium(I) and Iridium(III) Complexes Supported by a Diphenolate Imidazolyl-Carbene Ligand.' Organometallics 2010, 29, 89-100.

23. Golisz, S. R.; Hazari, N.; Labinger, J. A.; Bercaw, J. E. 'Activation of the C-N Bond in Nitromethane by Palladium a-Diimine Complexes.' J. Org. Chem. 2009, 74, 8441-8443.

22. Bercaw, John E.; Hazari, Nilay; Labinger, Jay A. 'Activation of a C-H Bond in Indene by [(COD)Rh(m₂-OH)]₂.' Organometallics 2009, 28,5489-5492.

21. Bercaw, John E.; Day, Michael W.; Golisz, Suzanne R.; Hazari, Nilay; Henling, Lawrence M.; Labinger, Jay A.; Schofer, Susan J.; Virgil, Scott. 'Robotic Lepidoptery: Structural Characterization of (mostly) Unexpected Palladium Complexes Obtained from High-Throughput Catalyst Screening.' Organometallics 2009, 28, 5017-5024.

20. Hazari, N.; Labinger, J. A.; Scott, V. J. 'A Mechanistic Explanation for Selectivity in the Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane): Moderate Acidity Allows Kinetic Control to Operate.' J. Catal. 2009, 263, 266-276.

19. Esposito, E.; Roberts, D. E.; Cloke, F. G. N.; Caddick, S.; Green, J. C.; Hazari, N.; Hitchcock, P. B. 'Carbon-Silicon Bond Activation by [Pd(ItBu)₂]; the Molecular Structures of [Pd(Me₃Si)(ItBu)(m-I)]₂ and [Pd(CH₂ItBu)I₂].' Eur. J. Inorg. Chem. 2009, 13, 1844-1850. Invited contribution to special issue on 'N-Heterocyclic Carbene Complexes'.

18. Bercaw, J. E.; Hazari, N.; Labinger, J. A.; Oblad, P. F. 'C-H Bond Activation by [{(Diimine)Pd(m-OH)}₂]²⁺ Dimers: Mechanism-Guided Catalytic Improvement.' Angew. Chem., Int. Ed. 2008, 47, 9941-9943. Selected as a hot article by the editors of Angew. Chem., Int. Ed.

17. Bercaw, J. E.; Hazari, N.; Labinger, J. A. 'Oxidative Aromatization of Olefins with Dioxygen Catalyzed by Palladium Trifluoroacetate.' J. Org. Chem. 2008, 73, 8654-8657.

16. Bercaw, J. E.; Hazari, N.; Labinger, J. A.; Scott, V. J.; Sunley, G. J. 'Selected Methylative Homologation: An Alternate Route to Alkane Upgrading.' J. Am. Chem. Soc. 2008, 130, 11988-11995.

15. Williams, T. J.; Caffyn, A. J. M.; Hazari, N.; Oblad, P. F.; Labinger, J. A.; Bercaw, J. E. 'C-H Bond Activation Mediated by Air-Stable [(diimine)MII(μ₂-OH)]₂²⁺ Dimers (M = Pd, Pt).' J. Am. Chem. Soc. 2008, 130, 2418-2419.

14. Bercaw, J. E.; Diaconescu, P. L.; Grubbs, R. H.; Hazari, N.; Kay, R. D.; Labinger, J. A.; Mehrkhodavandi, P.; Morris, G. E.; Sunley, G. J.; Vagner, P. 'The Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane) over Indium (III) Iodide.' Inorg. Chem. 2007, 46, 11371-11380.

13. Bercaw, J. E.; Grubbs, R. H.; Hazari, N.; Labinger, J. A.; Li, X. 'Enhanced Selectivity in the Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane) over Zinc Iodide by Added Phosphorous or Hypophosphorous Acid.' Chem. Commun. 2007, 2974-2976.

12. Brayshaw, S. K.; Green, J. C.; Hazari, N.; Weller, A. S. 'A DFT Based Investigation into the Electronic Structure and Properties of Hydride Rich Rhodium Clusters.' Dalton Trans. 2007, 1781-1792. Selected as a hot article by the editors of Dalton Trans.

11. Brayshaw, S. K.; Green, J. C.; Hazari, N.; McIndoe, J. S.; Marken, F.; Raithby, P. R.; Weller, A. S. 'Storing and Releasing Hydrogen with a Redox Switch.' Angew. Chem., Int. Ed. 2006, 45, 6005-6008. For more information on this work see: 'Quick Release, Hydrogen Storage.' Nature, 2006, 442, 850 or Takimoto, M.; Hou, Z. 'Hydrogen at the Flick of a Switch.' Nature, 2006, 443, 400-401.

10. Summerscales, O. T.; Cloke, F. G. N.; Hitchcock, P. B.; Green, J. C.; Hazari, N. 'Reductive Cyclotetramerization of CO to Squarate by a U(III) Complex; the X-ray Crystal Structure of [(U(h-C₈H₆{SiiPr₃-1,4}₂)(h-C₅Me₄H)]₂(m-h₂:h₂-C₄O₄).' J. Am. Chem. Soc. 2006, 128, 9602-9603.

9. Cloke, F. G. N.; Green, J. C.; Hazari, N.; Hitchcock, P. B.; Mountford, P.; Nixon, J. F.; Wilson, D. J. 'Reactions of tBuC≡P with Cyclooctatetraene-Supported Titanium Imido Complexes.' Organometallics 2006, 25, 3688-3700.

8. Dunn, S. C.; Hazari, N.; Cowley, A. R.; Green, J. C.; Mountford, P. 'Synthesis and Reactions of Group 4 Imido Complexes Supported by Cyclooctatetraene Ligands.' Organometallics 2006, 25, 1755-1770.

7. Summerscales, O. T.; Cloke, F. G. N.; Hitchcock, P. B.; Green, J. C.; Hazari, N. 'Reductive Cyclotrimerization of Carbon Monoxide to the Deltate Dianion by an Organometallic Uranium Complex.' Science 2006, 311, 829-831. For more information on this work see: Wayland, B.; Fu, X. 'Building Molecules with Carbon Monoxide Reductive Coupling.' Science 2006, 311, 790-791.

6. Decleva, P.; Fronzoni, G.; Stener, M.; de Simone, M.; Coreno, M.; Green, J. C.; Hazari, N.; Plekan, O. 'Strong Oscillations in Molecular Valence Photoemission Intensities.' Phys. Rev. Lett. 2005, 95, 263401/1-263401/4.

5. Parsons, T. B.; Hazari, N.; Cowley, A. R.; Green, J. C.; Mountford, P. 'Synthesis, Structures, and DFT Bonding Analysis of New Titanium Hydrazido(2-) Complexes.' Inorg. Chem. 2005, 44, 8442-8458.

4. Hazari, N.; Mountford, P. 'Reactions and Applications of Titanium Imido Complexes.' Acc. Chem. Res. 2005, 38, 839-849.

3. Dunn, S. C.; Hazari, N.; Jones, N. M.; Moody, A. G.; Blake, A. J.; Cowley, A. R.; Green, J. C.; Mountford, P. 'Titanium Imido Complexes of Cyclooctatetraenyl Ligands.' Chem. Eur. J. 2005, 11, 2111-2124.

2. Hazari, N.; Cowley, A. R.; Mountford, P. 'm-dichloro-bis[chloro[N-tertbutylimido]bis(pyridine-N)titanium(IV)].' Acta Crystallogr. 2004, E60, m1844-m1846.

1. Field, L. D.; Hazari, N.; Li, H.; Luck, I. J. 'Dynamic 15N NMR Studies of Iron Phosphine Complexes Containing Coordinated Dinitrogen.' Magn. Reson. Chem. 2003, 41, 709-713.

Patents

1. Labinger, J. A.; Sunley, G. J.; Hazari, N.; Iglesia, E. I.; Scott, V. J. 'Process for the Production of a Hydrocarbon'. PCT Int. Appl. 2009, WO 2009064622.

Book Chapters

1. 'Titanium Complexes in the Oxidation State +III'. N. Hazari and P. Mountford in Comprehensive Organometallic Chemistry III, Eds. R. H. Crabtree and D. M. P. Mingos, Elsevier, New York, 2006, Volume 4, 281-322.

	Publications 62. Bielinski, E. A.; Dai, W.; Guard, L. M.; Hazari, N.; Takase, M. K. 'Synthesis, Properties and Reactivity Studies of Palladium and Nickel NHC Complexes Supported by Combinations of Allyl, Cyclopentadienyl, and Indenyl Ligands.' Organometallics 2013, In Press. 61. Guard, L. M.; Hazari, N. 'Synthesis and Reactivity of Magnesium Complexes Supported by Tris(2-dimethylaminoethyl)amine (Me6tren).' Organometallics 2013, In Press. 60. Bernskoetter, W. H.; Hazari, N. 'A Computational Investigation of the Insertion of Carbon Dioxide into Four and Five Coordinate Iridium Hydrides.' Eur. J. Inorg. Chem. 2013, In Press. Invited contribution to 'Small Molecule Activation by Reactive Metal Complexes' issue. 59. Jin, D.; Schmeier, T. J.; Williard, P. G.; Hazari, N.; Bernskoetter, W. H. 'Lewis Acid Induced β-Elimination from a Nickelalactone-Efforts Toward Acrylate Production from CO2 and Ethylene.' Organometallics 2013, 32, 2152-2159. 58. Huang, J.-S.; Goh, T.; Li, X.; Sfeir, M.; Bielinski, E. A.; Tomasulo, S.; Lee, M. L.; Hazari, N.; Taylor, A. D. 'Polymer Bulk Heterojunction Solar Cells Employing Förster Resonance Energy Transfer.' Nat. Photonics 2013, In Press. 57. Wu, J.; Dai, W.; Farnaby, J. H.; Hazari, N.; Le Roy, J. J.; Mereacre, V.; Murugesu, M.; Powell, A. K.; Takase, M. K. 'Synthesis and Catalytic Activity of Iron Complexes with Bidentate NHC Ligands.' Dalton Trans. 2013, 42, 7404-7413. Invited contribution to 'N-Heterocyclic Carbene' issue. 56. Collom, S. L.; Anastas, P. T.; Beach, E. S.; Crabtree, R. H.; Hazari, N.; Sommer, T. 'Differing Selectivities in Mechanochemical versus Conventional Solution Oxidation using Oxone.' Tetrahedron Lett. 2013, 54, 2344-2347. 55. Durrell, A. C.; Jackson, M. N.; Hazari, N.; Gray, H. B. 'Making Carbon-Chlorine Bonds by Dipalladium Electrocatalysis.' Eur. J. Inorg. Chem. 2013, 1134-1137. 54. Dau, P. D.; Hruszkewcyz, D. P.; Huang, D.-L.; Chalkley, M. J.; Liu, H.-T.; Green, J. C.; Hazari, N.; Wang, L.-S. 'Photoelectron Spectroscopy of Pd(I) Dimers with Bridging Allyl Ligands.' Organometallics 2012, 31, 8571-8576. 53. Suh, H. W.; Schmeier, T. J.; Hazari, N.; Kemp, R. A. 'Experimental and Computational Studies of the Reaction of Carbon Dioxide with Pincer Supported Nickel and Palladium Hydrides.' Organometallics 2012, 31, 8225-8236. 52. Graeupner, J.; Brewster, T. P.; Blakemore, J. D.; Schley, N. D.; Thomsen, J. M.; Brudvig, G. W.; Hazari, N.; Crabtree, R. H. 'Preparation of Electron-Rich CpIr(biphenyl-2,2’-diyl) Complexes with p-Accepting Carbon Donor Ligands.' Organometallics 2012, 31, 7158-7164. 51. Dobereiner, G. E.; Wu, J.; Manas, M. G.; Schley, N. D.; Takase, M. K.; Crabtree, R. H.; Hazari, N.; Nova, A.; Maseras, F. 'Mild, Reversible Reaction of Iridium(III) Amido Complexes with Carbon Dioxide.' Inorg. Chem. 2012, 51, 9683-9693. 50. Luca, O. R.; Blakemore, J. D.; Praetorius, J. M.; Schmeier, T. J.; Hunsinger, G. B.; Brudvig, G. W.; Hazari, N.; Crabtree, R. H. 'Nickel Pincer Complexes for the Electrocatalytic Production of Hydrogen.' Inorg. Chem. 2012, 51, 8704-8709. 49. Guard, L. M.; Palma, J. L.; Stratton, W. P.; Allen, L. J.; Brudvig, G. W.; Crabtree, R. H.; Batista, V. S.; Hazari, N.; 'Synthesis and Computational Studies of Mg Complexes Supported by 2,2':6,2''-Terpyridine Ligands.' Dalton Trans. 2012, 41, 8098-8110. Invited contribution to 'New Talent in the America's Issue'. 48. Schmeier, T. J.; Nova, A.; Hazari, N.; Maseras, F. 'Synthesis of PCP Supported Nickel Complexes and their Reactivity with Carbon Dioxide.' Chem. Eur. J. 2012, 18, 6915-6927. 47. Wu, J.; Faller, J. W.; Hazari, N.; Schmeier, T. J. 'Stoichiometric and Catalytic Reactions of Thermally Stable Ni(0) NHC Complexes.' Organometallics, 2012, 31, 806-809 . 46. Hazari, N.; Labinger, J. A.; Igelsia, E: Simenotti, D. A. 'Selective Homogeneous and Heterogeneous Catalytic Conversion of Methanol/Dimethyl Ether to Triptane.' Acc. Chem. Res. 2012, 45, 653-662 . 45. Hruszkewycz, D. P.; Wu, J.; Green, J. C.; Hazari, N.; Schmeier, T. J. 'Mechanistic Studies of the Insertion of CO₂ into Palladium(I) Bridging Allyl Dimers.' Organometallics 2012, 31, 470-485. For more information on this work see: Patton, R. S.; Brown, J. M. 'Dinuclear Palladium Complexes – Precursors of Catalysts?' Angew. Chem. Int. Ed. 2012, 51,10448-10450. 44. Ashley, J. M.; Farnaby, J. H.; Hazari, N.; Kim, K. E.; Luzik Jr, E. D.; Meehan, R. E.; Meyer, E. B.; Schley, N. D.; Schmeier, T. J.; Tailor, A. N. 'Axially Chiral Dimeric Ir and Rh Complexes Bridged by Flexible NHC Ligands.' Inorg. Chim. Acta 2012, 380, 399-410. Invited contribution to 'Young Investigator Award Issue'. 43. Brewster, T. P.; Ding, W.; Schley, N. D.; Hazari, N.; Batista, V. S.; Crabtree, R. H. 'Thiocyanate Linkage Isomerism in a Ruthenium Polypyridyl Complex.' Inorg. Chem. 2011, 50, 11938-11946. 42. Aitken, G.; Hazari, N.; Frey, A. S. P.; Cloke, F. G. N.; Summerscales, O.; Green, J. C. 'Reductive Coupling of Carbon Monoxide by U(III) Complexes – a Computational Study.' Dalton Trans. 2011, 40, 11080-11088. Selected as a hot article by the editors of Dalton Trans. 41. Schmeier, T. J.; Dobereiner, G. E.; Crabtree, R. H.; Hazari, N. 'Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO₂ Reduction Catalyst.' J. Am. Chem. Soc. 2011, 133, 9274-9277. 40. Wu, J.; Hazari, N.; Incarvito, C. D. 'Synthesis, Properties and Reactivity with Carbon Dioxide of (allyl)₂Ni(L) Complexes.' Organometallics 2011, 30, 3142-3150. 39. Hazari, N.; Hruszkewycz, D. P.; Wu, J. 'Pd(I) Bridging Allyl Dimers: A New System for the Catalytic Functionalization of Carbon Dioxide.' Synlett 2011, 13, 1793-1797. Invited SYNPACT review article. 38. Dobereiner, G. E.; Nova, A.; Schley, N. D.; Hazari, N.; Miller, S. J.; Eisenstein, O.; Crabtree, R. H. 'Iridium-Catalyzed Hydrogenation of N-Heterocyclic Compounds under Mild Conditions by an Outer Sphere Pathway.' J. Am. Chem. Soc. 2011, 133, 7547-7562. 37. Blakemore, J. D.; Chalkley, M. J.; Farnaby, J. H.; Guard, L. M.; Hazari, N.; Incarvito, C. D.; Luzik Jr, E. D.; Suh, H. W. 'New Bidentate Trans-Chelating N-Heterocyclic Carbene Ligands for Palladium.' Organometallics 2011, 30, 1818-1829. 36. Hruszkewycz, D. P.; Wu, J.; Hazari, N.; Incarvito, C. D. 'Palladium(I) Bridging Allyl Dimers for the Catalytic Functionalization of CO₂.' J. Am. Chem. Soc. 2011, 133, 3280-3283. Selected as a Science and Technology Concentrate in Chemical & Engineering News. 35. Brewster, T. P.; Blakemore, J. D.; Schley, N. D.; Incarvito, C. D.; Hazari, N.; Brudvig, G. W.; Crabtree, R. H. 'An Iridium(IV) Species, [CpIr(NHC)Cl]⁺, Related to a Water-Oxidation Catalyst.' Organometallics* 2011, 30, 965-973. 34. Marino, N.; Fazen, C. H.; Blakemore, J. D.; Incarvito, C. D.; Hazari, N.; Doyle, R. P. 'Isostructural Pd^II and Pt^II Pyrophosphato Complexes: Polymorphism and Unusual Bond Character in d⁸-d⁸ Systems.' Inorg. Chem. 2011, 50, 2507-2520. 33. Shuman, N. S.; Miller, T. M.; Viggiano, A. A.; Luzik Jr, E. D.; Hazari, N. 'Kinetics of Electron Attachment to SF₃CN, SF₃C₆F₅, and SF₃ and Mutual Neutralization of Ar⁺ with CN^- and C₆F₅^-.' J. Chem. Phys. 2011, 134, 044323/1-044323/7. 32. Schmeier, T. J.; Hazari, N.; Incarvito, C. D.; Raskatov, J. R. 'Exploring the Reactions of CO₂ with PCP Supported Nickel Complexes.' Chem. Commun. 2011, 47, 1824-1826. 31. Wu, J.; Hazari, N. 'Palladium Catalyzed Carboxylation of Allylstannanes and Boranes Using CO₂.' Chem. Commun. 2011, 47, 1069-1071. 30. Shuman, N. S.; Miller, T. M.; Hazari, N.; Luzik Jr, E. D.; Viggiano, A. A. 'Kinetics Following Addition of Sulfur Fluorides to a Weakly Ionized Plasma from 300 K to 500 K: Rate Constants and Product Determinations for Ion-ion Mutual Neutralization and Thermal Electron Attachment to SF₅, SF₃, and SF₂^-.' J. Chem. Phys. 2010, 133, 234304/1-234304/11. 29. Wu, J.; Green, J. C.; Hazari, N.; Hruszkewycz, D. P.; Incarvito, C. D.; Schmeier, T. J. 'The Reaction of Carbon Dioxide with Palladium Allyl Bonds.' Organometallics 2010, 29, 6369-6376. 28. Hazari, N. 'Homogeneous Iron Complexes for the Conversion of Dinitrogen into Ammonia and Hydrazine.' Chem. Soc. Rev. 2010, 4044-4056. 27. Durrell, A. C.; Gray, H. B.; Hazari, N.; Incarvito, C. D.; Liu, J.; Yan, E. C. 'Tris(hydroxypropyl)phosphine Oxide: A Chiral 3D Material with Non-Linear Optical Properties.' Cryst. Growth Des. 2010, 10, 1482-1485. 26. Bercaw, J. E.; Durrell, A. C.; Gray, H. B.; Green, J. C.; Hazari, N.; Labinger, J. A.; Winkler, J. R. 'Electronic Structures of Pd(II) Dimers.' Inorg. Chem. 2010, 49, 1801-1810. 25. Oblad, P. F.; Hazari, N.; Labinger, J. A.; Bercaw, J. E. 'Oxidation of Organometallic Platinum and Palladium Complexes Obtained from C-H Activation.' Organometallics 2010, 29, 789-794. 24. Weinberg, D. R.; Hazari, N.; Labinger, J. A.; Bercaw, J. E. 'Iridium(I) and Iridium(III) Complexes Supported by a Diphenolate Imidazolyl-Carbene Ligand.' Organometallics 2010, 29, 89-100. 23. Golisz, S. R.; Hazari, N.; Labinger, J. A.; Bercaw, J. E. 'Activation of the C-N Bond in Nitromethane by Palladium a-Diimine Complexes.' J. Org. Chem. 2009, 74, 8441-8443. 22. Bercaw, John E.; Hazari, Nilay; Labinger, Jay A. 'Activation of a C-H Bond in Indene by [(COD)Rh(m₂-OH)]₂.' Organometallics 2009, 28,5489-5492. 21. Bercaw, John E.; Day, Michael W.; Golisz, Suzanne R.; Hazari, Nilay; Henling, Lawrence M.; Labinger, Jay A.; Schofer, Susan J.; Virgil, Scott. 'Robotic Lepidoptery: Structural Characterization of (mostly) Unexpected Palladium Complexes Obtained from High-Throughput Catalyst Screening.' Organometallics 2009, 28, 5017-5024. 20. Hazari, N.; Labinger, J. A.; Scott, V. J. 'A Mechanistic Explanation for Selectivity in the Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane): Moderate Acidity Allows Kinetic Control to Operate.' J. Catal. 2009, 263, 266-276. 19. Esposito, E.; Roberts, D. E.; Cloke, F. G. N.; Caddick, S.; Green, J. C.; Hazari, N.; Hitchcock, P. B. 'Carbon-Silicon Bond Activation by [Pd(ItBu)₂]; the Molecular Structures of [Pd(Me₃Si)(ItBu)(m-I)]₂ and [Pd(CH₂ItBu)I₂].' Eur. J. Inorg. Chem. 2009, 13, 1844-1850. Invited contribution to special issue on 'N-Heterocyclic Carbene Complexes'. 18. Bercaw, J. E.; Hazari, N.; Labinger, J. A.; Oblad, P. F. 'C-H Bond Activation by [{(Diimine)Pd(m-OH)}₂]²⁺ Dimers: Mechanism-Guided Catalytic Improvement.' Angew. Chem., Int. Ed. 2008, 47, 9941-9943. Selected as a hot article by the editors of Angew. Chem., Int. Ed. 17. Bercaw, J. E.; Hazari, N.; Labinger, J. A. 'Oxidative Aromatization of Olefins with Dioxygen Catalyzed by Palladium Trifluoroacetate.' J. Org. Chem. 2008, 73, 8654-8657. 16. Bercaw, J. E.; Hazari, N.; Labinger, J. A.; Scott, V. J.; Sunley, G. J. 'Selected Methylative Homologation: An Alternate Route to Alkane Upgrading.' J. Am. Chem. Soc. 2008, 130, 11988-11995. 15. Williams, T. J.; Caffyn, A. J. M.; Hazari, N.; Oblad, P. F.; Labinger, J. A.; Bercaw, J. E. 'C-H Bond Activation Mediated by Air-Stable [(diimine)MII(μ₂-OH)]₂²⁺ Dimers (M = Pd, Pt).' J. Am. Chem. Soc. 2008, 130, 2418-2419. 14. Bercaw, J. E.; Diaconescu, P. L.; Grubbs, R. H.; Hazari, N.; Kay, R. D.; Labinger, J. A.; Mehrkhodavandi, P.; Morris, G. E.; Sunley, G. J.; Vagner, P. 'The Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane) over Indium (III) Iodide.' Inorg. Chem. 2007, 46, 11371-11380. 13. Bercaw, J. E.; Grubbs, R. H.; Hazari, N.; Labinger, J. A.; Li, X. 'Enhanced Selectivity in the Conversion of Methanol to 2,2,3-Trimethylbutane (Triptane) over Zinc Iodide by Added Phosphorous or Hypophosphorous Acid.' Chem. Commun. 2007, 2974-2976. 12. Brayshaw, S. K.; Green, J. C.; Hazari, N.; Weller, A. S. 'A DFT Based Investigation into the Electronic Structure and Properties of Hydride Rich Rhodium Clusters.' Dalton Trans. 2007, 1781-1792. Selected as a hot article by the editors of Dalton Trans. 11. Brayshaw, S. K.; Green, J. C.; Hazari, N.; McIndoe, J. S.; Marken, F.; Raithby, P. R.; Weller, A. S. 'Storing and Releasing Hydrogen with a Redox Switch.' Angew. Chem., Int. Ed. 2006, 45, 6005-6008. For more information on this work see: 'Quick Release, Hydrogen Storage.' Nature, 2006, 442, 850 or Takimoto, M.; Hou, Z. 'Hydrogen at the Flick of a Switch.' Nature, 2006, 443, 400-401. 10. Summerscales, O. T.; Cloke, F. G. N.; Hitchcock, P. B.; Green, J. C.; Hazari, N. 'Reductive Cyclotetramerization of CO to Squarate by a U(III) Complex; the X-ray Crystal Structure of [(U(h-C₈H₆{SiiPr₃-1,4}₂)(h-C₅Me₄H)]₂(m-h₂:h₂-C₄O₄).' J. Am. Chem. Soc. 2006, 128, 9602-9603. 9. Cloke, F. G. N.; Green, J. C.; Hazari, N.; Hitchcock, P. B.; Mountford, P.; Nixon, J. F.; Wilson, D. J. 'Reactions of tBuC≡P with Cyclooctatetraene-Supported Titanium Imido Complexes.' Organometallics 2006, 25, 3688-3700. 8. Dunn, S. C.; Hazari, N.; Cowley, A. R.; Green, J. C.; Mountford, P. 'Synthesis and Reactions of Group 4 Imido Complexes Supported by Cyclooctatetraene Ligands.' Organometallics 2006, 25, 1755-1770. 7. Summerscales, O. T.; Cloke, F. G. N.; Hitchcock, P. B.; Green, J. C.; Hazari, N. 'Reductive Cyclotrimerization of Carbon Monoxide to the Deltate Dianion by an Organometallic Uranium Complex.' Science 2006, 311, 829-831. For more information on this work see: Wayland, B.; Fu, X. 'Building Molecules with Carbon Monoxide Reductive Coupling.' Science 2006, 311, 790-791. 6. Decleva, P.; Fronzoni, G.; Stener, M.; de Simone, M.; Coreno, M.; Green, J. C.; Hazari, N.; Plekan, O. 'Strong Oscillations in Molecular Valence Photoemission Intensities.' Phys. Rev. Lett. 2005, 95, 263401/1-263401/4. 5. Parsons, T. B.; Hazari, N.; Cowley, A. R.; Green, J. C.; Mountford, P. 'Synthesis, Structures, and DFT Bonding Analysis of New Titanium Hydrazido(2-) Complexes.' Inorg. Chem. 2005, 44, 8442-8458. 4. Hazari, N.; Mountford, P. 'Reactions and Applications of Titanium Imido Complexes.' Acc. Chem. Res. 2005, 38, 839-849. 3. Dunn, S. C.; Hazari, N.; Jones, N. M.; Moody, A. G.; Blake, A. J.; Cowley, A. R.; Green, J. C.; Mountford, P. 'Titanium Imido Complexes of Cyclooctatetraenyl Ligands.' Chem. Eur. J. 2005, 11, 2111-2124. 2. Hazari, N.; Cowley, A. R.; Mountford, P. 'm-dichloro-bis[chloro[N-tertbutylimido]bis(pyridine-N)titanium(IV)].' Acta Crystallogr. 2004, E60, m1844-m1846. 1. Field, L. D.; Hazari, N.; Li, H.; Luck, I. J. 'Dynamic 15N NMR Studies of Iron Phosphine Complexes Containing Coordinated Dinitrogen.' Magn. Reson. Chem. 2003, 41, 709-713. Patents 1. Labinger, J. A.; Sunley, G. J.; Hazari, N.; Iglesia, E. I.; Scott, V. J. 'Process for the Production of a Hydrocarbon'. PCT Int. Appl. 2009, WO 2009064622. Book Chapters 1. 'Titanium Complexes in the Oxidation State +III'. N. Hazari and P. Mountford in Comprehensive Organometallic Chemistry III, Eds. R. H. Crabtree and D. M. P. Mingos, Elsevier, New York, 2006, Volume 4, 281-322.